Magnetic Circular Dichroism of Cu(acac)2, Fe(acac)3, and Co(acac)3
نویسندگان
چکیده
منابع مشابه
Organic Chemical Applications of Magnetic Circular Dichroism*
Recent applications of magnetic circular dichroism spectroscopy (the Faraday effect) in organic chemistry are reviewed. Magnetic optical activity is a universal property of all matter and consequently can be applied to optically active as well as optically inactive molecules. It is emphasized, however, that natural and magnetic optical activity have separate physical origins and the information...
متن کاملMagnetic circular dichroism of peralkylated tetrasilane conformers.
Magnetic circular dichroism (MCD) of five peralkylated tetrasilanes (1-5) conformationally constrained to angles ranging from nearly 0 degrees to 180 degrees and of the open chain tetrasilane Si(4)Me(10) (6) shows a clear conformational dependence and permits the detection of previously hidden transitions. In the tetrasilane CH(2)Si(4)Me(8) (1), with the smallest dihedral angle, comparison of M...
متن کاملMagnetic Circular Dichroism of Paramagnetic Species
Magnetic circular dichroism (MCD) spectroscopy and variable-temperature variable-field (VTVH) MCD are powerful methods for studying the excited and ground states of paramagnetic systems. Notably, these methods provide detailed insight into the geometric and electronic structures of catalytically active centers in inorganic and biological systems. In this review, we present the theoretical backg...
متن کاملCircular dichroism of planar chiral magnetic metamaterials.
We propose, fabricate, and study a double-layer chiral planar metamaterial that exhibits pronounced circular dichroism at near-infrared wavelengths. The antisymmetric oscillation modes of the two coupled layers allow local magnetic-dipole moments and enhanced polarization effects compared with similar single-layer systems where only electric-dipole moments occur. Experiment and rigorous theoret...
متن کاملMagnetic Circular Dichroism Spectroscopy of Metalloporphyrins
Many enzymes contain metalloporphyrins as prosthetic groups, which catalyse a vide variety of biologically important reactions. Hence, these species have been studied by a large number of spectroscopic techniques including Magnetic Circular Dichroism Spectroscopy (MCD). This method is especially useful to investigate the electronic structures and spectra of paramagnetic complexes [1]. However, ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1973
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.46.636